This is a modified version of an article written by Matt Shipman, Research Lead in University Communications.
Researchers from Prof. Michael Dickey’s research group in CBE and Prof. Karen Daniels’ research group in the NCSU Department of Physics have developed a technique that allows them to produce streams of liquid metal at room temperature, which is a highly unusual behavior.
“Liquids want to form droplets, because that lowers their surface energy,” says Prof. Dickey, a co-corresponding author of an article about the work. “And that’s especially true for liquid metals, because they have much higher surface tension than other liquids.”
Surface tension is measured in units of millinewtons per meter. Most liquids, such as gasoline or water, have surface tension values between 20 and 72 millinewtons per meter. Gallium alloys, which were used in the study, have a surface tension of at least 500 millinewtons per meter. By applying a low voltage to the liquid metal, the researchers were able to tune its surface tension across at least three orders of magnitude.
“We can lower the surface tension from 500 to 0.1 by applying less than one volt,” says Dr. Minyung Song (Ph.D. ’20), a graduate from Prof. Dickey’s group and first author of a paper describing the work. “And that completely changes how the liquid metal behaves.”
If you started squeezing gallium indium alloy out of a nozzle, it forms into a droplet due to its high surface tension. If you wanted to create a stream of liquid metal, you’d have to apply a high enough flow-rate to eject it rapidly from the nozzle. But even then, the resulting stream wouldn’t be very stable.
However, applying a low voltage to the liquid metal when the metal is under water creates a thin layer of oxide at the surface. This allows the researchers to create running streams of liquid metal that have the diameter of a human hair – and a low flow-rate. Video of experiments demonstrating the technique can be seen here.
“This oxide acts like soap molecules do for water, lowering the surface tension and reducing the fluid’s tendency to bead up,” says Prof. Daniels, a co-corresponding author of the study, “but here the effect is completely reversible by turning off the voltage. You can’t easily take the soap back out of the water.”
When the low voltage is applied to moving liquid metal, it effectively creates a flowing oxide skin that runs along the surface of the liquid metal. In other words, the oxide layer isn’t static – the whole thing flows steadily out of the nozzle, like a wire.
The technique gives researchers a great deal of control over how the liquid metal behaves, because – up to a point – the higher the voltage they apply to the liquid metal, the lower the liquid metal’s surface tension. However, at the highest voltages, the oxide layer forms a thick crust that disrupts the way the metal flows. This results in a fluid flow that resembles dripping wax.
The research team had previously shown that applying low voltage to a liquid metal droplet at rest lowers its surface tension and causes it to form fractal patterns. A video from an earlier article about the fractal-forming behavior is available here. That study was also performed on liquid metal underwater. This new study is the first to address what happens when the liquid metal is in motion.
“We’re only beginning to explore the full range of potential applications for this technique,” Dickey says. “One idea would be to effectively create liquid metal wires at room temperature. If you encase them in an elastic sheath, you’d have stretchable wires. It could also be used as a new tool for studying and controlling fluid behavior. It’s exciting because more than 100 years of scientific studies show liquid streams break up into droplets. We have found a simple way to stabilize these streams.”
The study, “Overcoming Rayleigh Plateau Instabilities: Stabilizing and Destabilizing Liquid Metal Streams via Electrochemical Oxidation,” is published in Proceedings of the National Academy of Sciences. The paper was co-authored by Karin Kartawira, a high school student; former members of Prof. Dickey’s research group Dr. Collin Eaker (Ph.D. ’16); Cheng Li, a visiting graduate student from China; Keith Hillaire, a graduate student in Prof. Daniels’ research group; and Abolfazl Kiani, a visiting scholar in Prof. Dickey’s research group.
The work was done with support from the National Science Foundation, under grants CBET-1510772 and DMR-160897.